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Volltext Schmid_Christina.pdf1.pdf (6,7 MB)
URN (für Zitat) http://nbn-resolving.org/urn:nbn:de:swb:90-292444
Titel Efficient Switching of RAFT to Hydroxyl Capped Polymers as a Versatile Scaffold for Block Copolymer Synthesis
Autor Schmid, Christina Maria
Institution Institut für Technische Chemie und Polymerchemie (ITCP)
Dokumenttyp Buch
Verlag Karlsruhe
Jahr 2012
Hochschulschrift Dissertation
Fakultät für Chemie und Biowissenschaften (CHEM-BIO)
Institut für Technische Chemie und Polymerchemie (ITCP)
Prüfungsdaten: 20.07.2012
Referent/Betreuer: Prof. C. Barner-Kowollik
Abstract The RAFT polymerization is a versatile technique to synthesize polymers with narrow dispersity and high chain-end functionality. To enable a switch from RAFT to other polymerization protocols, the RAFT polymers were transformed via a novel end-group conversion into OH functional polymers. The procedure was employed to synthesize a variety of sulfur-free (multi-) block (star) copolymers. The complex polymers were analyzed via LCCC-SEC, SEC/ESI-MS, and SEC/FT-IR.